Independent Career

24. Effects of a triangular nanocage structure on the binding of neutral and anionic ligands to Co^II and Zn^II porphyrins.
P. Thomas Blackburn, Mark C. Lipke J. Coord. Chem. 2022, 75, 1520 – 1542.
*Included in Emerging Leaders In Coordination Chemistry special issue.

23. Gram-scale synthesis of a covalent nanocage that preserves the redox properties of encapsulated fullerenes.
Daniel A. Rothschild, William P. Kopcha, Aaron Tran, Jianyuan Zhang, Mark C. Lipke Chem. Sci. 2022, 13, 5325 – 5332.
*Highlighted in Chemistry Views, the magazine of Chemistry Europe.

22. Twisted A-D-A Type Acceptors with Thermally-Activated Delayed Crystallization Behavior for Efficient Nonfullerene Organic Solar Cells.
Yilei Wu, Sebastian Schneider, Yue Yuan, Ryan M. Young, Tommaso Francese, Iram F. Mansoor, Peter J. Dudenas, Yusheng Lei, Enrique D. Gomez, Dean M. DeLongchamp, Mark C. Lipke, Giulia Galli, Michael R. Wasielewski, John B. Asbury, Michael F. Tooney, Zhenan Bao Adv. Energy. Mater. 2022, 12, 2103957.

21. Accessing three oxidation states of cobalt in M₆L₃ nanoprisms with cobalt-porphyrin walls.
P. Thomas Blackburn, Iram F. Mansoor, Kaitlyn G. Dutton, Alexei M. Tyryshkina, Mark C. Lipke Chem. Commun. 2021, 57, 11342 – 11345.
*Included in Chemical Communications Emerging Investigator special issue.

20. Uptake, trapping, and release of organometallic cations by redox-active cationic hosts.
Iram F. Mansoor,* Kaitlyn G. Dutton,* Daniel A. Rothschild, Richard C. Remsing, Mark C. Lipke J. Am. Chem. Soc. 2021, 143, 16993 – 17003.
*These authors contributed equally.

19. Unexpected Formation of Metallofulleroids from Multicomponent Reactions, with Crystallographic and Computational Studies of the Cluster Motion.
Yanbang Li, Thomas J. Emge, Antonio Moreno-Vicente, William P. Kopcha, Yue Sun, Iram F. Mansoor, Mark C. Lipke, Gene S. Hall, Josep M. Poblet, Antonio Rodríguez-Fortea, Jianyuan Zhang Angew. Chem. Int. Ed. 2021, 60, 25269 – 25273.

18. Correcting frost diagram misconceptions using interactive frost diagrams.
Kaitlyn G. Dutton, Mark C. Lipke J. Chem. Educ. 2021, 98, 2578 – 2583.

17. A delocalized cobaltoviologen with seven reversibly accessible redox states and highly tunable electrochromic behaviour.
Iram F. Mansoor, Derek I. Wozniak, Yilei Wu, Mark C. Lipke Chem. Commun. 2021, 56, 13864 – 13867.

16. The Influence of Redox-Active Linkers on the Stability and Physical Properties of a Highly Electroactive Porphyrin Nanoprism.
Kaitlyn G. Dutton, Daniel A. Rothschild, Dakota B. Pastore, Thomas J. Emge, Mark C. Lipke Inorg. Chem. 2020, 59, 12616 – 12624.

15. Modeling the structure and infrared spectra of omega-3 fatty acid esters.
Wenting Meng, Yaoyukun Jiang, Daniel A. Rothschild, Mark C. Lipke, Gene Hall, Lu Wang J. Chem. Phys. 2020, 153, 035101.

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Mentored

14. A Redox-Switchable Molecular Zipper.
Dumartin, M.; Lipke, M. C.*; Stoddart, J. F.* J. Am. Chem. Soc. 2019, 141, 18308 – 18317.

13. Catalytic Olefin Hydrosilations Mediated by Ruthenium η³-H₂Si σ-Complexes of Primary and Secondary Silanes.
Lipke, M. C.; Poradowski, M.-N.; Raynaud, C.; Eisenstein, O.; Tilley, T. D. ACS Catal. 2018, 8, 11513 – 11523.

12. Molecular Russian Dolls.
Cai, K.; Lipke, M. C.; Liu, Z.; Cheng, T.; Nelson, J.; Han, J.; Shi, Y.; Cheng, C.; Shen, D.; Stern, C. L.; Wasielewski, M. R.; Goddard III, W. A.; Stoddart, J. F. Nat. Commun. 2018, 9, 5275.

11. Shuttling Rates, Electronic States, and Hysteresis in a Ring-In-Ring Rotaxane.
Lipke, M. C.; Wu, Y.; Roy, I.; Wang, Y.; Wasielewski, M. R.; Stoddart, J. F. ACS Cent. Sci. 2018, 4, 362 – 371.

10. Size-Matched Radical Multivalency.
Lipke, M. C.; Cheng, T.; Wu, Y.; Arslan, H.; Xiao, H.; Wasielewski, M. R.; Goddard III, W. A.; Stoddart, J. F. J. Am. Chem. Soc. 2017, 139, 3986 – 3998.

9. Electrophilic Activation of Silicon-Hydrogen Bonds in Catalytic Hydrosilations.
Lipke, M. C.; Liberman-Martin, A. L.; Tilley, T. D. Angew. Chem. Int. Ed. 2016, 56, 2260 – 2294.

8. Significant Cooperativity Between Ruthenium and Silicon in Catalytic Transformations of an Isocyanide.
Lipke, M. C.; Liberman-Martin, A. L.; Tilley, T. D. J. Am. Chem. Soc. 2016, 138, 9704 – 9713.

7. Hypercoordinate Ketone Adducts of Electrophilic η³-H₂SiRRꞌ Ligands on Ruthenium as Key Intermediates for the Efficient and Robust Hydrosilation of Ketones.
Lipke, M. C.; Tilley, T. D. J. Am. Chem. Soc. 2014, 136, 16387 – 16398.

6. Interconversion of η³-H₂SiRRꞌ complexes and 16-Electron Silylene Complexes via Reversible H—H or C—H Elimination.
Lipke, M. C.; Neumeyer, F.; Tilley, T. D. J. Am. Chem. Soc. 2014, 136, 6092 – 6102.

5. Structural and Mechanistic Investigation of a Cationic Hydrogen-Substituted Ruthenium Silylene Catalyst for Olefin Hydrosilation.
Fasulo, M.; Lipke, M. C.; Tilley, T. D. Chem. Sci. 2013, 4, 3882 – 3887.

4. Silane-Isocyanide Coupling Involving 1,1-Insertion of XylNC into the Si—H Bond of a σ-Silane Ligand.
Lipke, M. C.; Tilley, T. D. J. Am. Chem. Soc. 2013, 135, 10298 – 10301.

3. Stabilization of ArSiH₄^– and SiH₆^2- Anions in Diruthenium Si—H σ-Complexes.
Lipke, M. C.; Tilley, T. D. Angew. Chem., Int. Ed. 2012, 51, 11115 – 11121.

2. High Electrophilicity at Silicon in η³-Silane σ-Complexes: Lewis Base Adducts of a Silane Ligand, Featuring Octahedral Silicon and Three Ru—H—Si Interactions.
Lipke, M. C.; Tilley, T. D. J. Am. Chem. Soc. 2011, 133, 16374 – 16377.

1. m-Terphenyl Anchored Palladium Diphosphinite PCP Pincer Complexes that Promote the Suzuki-Miyaura Reaction Under Mild Conditions.
Lipke, M. C.; Woloszynek, R. A.; Ma, L.; Protasiewicz, J. D. Organometallics 2009, 28, 188 – 196.